Bindungen beim Benzol: Unterschied zwischen den Versionen
Aus Chemie digital
(19 dazwischenliegende Versionen von einem Benutzer werden nicht angezeigt) | |||
Zeile 33: | Zeile 33: | ||
− | '''Anzeige der Orbitale bei einem C-Atom''' | + | '''Anzeige der Orbitale bei einem C-Atom und dem verbundenen H-Atom''' |
− | + | ||
<jmol> | <jmol> | ||
<jmolRadioGroup> | <jmolRadioGroup> | ||
<item> | <item> | ||
− | + | <script>select all;lcaocartoon delete; select (atomno=1); lcaocartoon color orange translucent 0.2; lcaocartoon scale 1; lcaocartoon create sp2a; lcaocartoon create sp2c; lcaocartoon create sp2b</script> | |
− | <script>lcaocartoon delete; select (atomno=1); lcaocartoon color orange translucent 0.2; lcaocartoon scale 1; lcaocartoon create sp2a; lcaocartoon create sp2c; lcaocartoon create sp2b</script> | + | |
<text>Anzeige der sp2-Orbitale</text> | <text>Anzeige der sp2-Orbitale</text> | ||
</item> | </item> | ||
<item> | <item> | ||
− | <script>lcaocartoon delete; select (atomno=1); lcaocartoon color blue translucent 0.1; lcaocartoon scale 1.6; lcaocartoon create pz | + | <script>select all;lcaocartoon delete; select (atomno=1); lcaocartoon color blue translucent 0.1; lcaocartoon scale 1.6; lcaocartoon create pz</script> |
<text>Anzeige des p-Orbitals</text> | <text>Anzeige des p-Orbitals</text> | ||
</item> | </item> | ||
<item> | <item> | ||
− | <script>lcaocartoon delete; select (atomno=1); lcaocartoon color blue translucent 0.1; lcaocartoon scale 1. | + | <script>select all;lcaocartoon delete; select (atomno=1); lcaocartoon color blue translucent 0.1; lcaocartoon scale 1.8; lcaocartoon create pz; select (atomno=1); lcaocartoon color orange translucent 0.2; lcaocartoon scale 1; lcaocartoon create sp2a; lcaocartoon create sp2c; lcaocartoon create sp2b</script> |
<text>Anzeige aller Orbitale des C-Atoms</text> | <text>Anzeige aller Orbitale des C-Atoms</text> | ||
</item> | </item> | ||
<item> | <item> | ||
− | <script>lcaocartoon delete; select (atomno=7); lcaocartoon color yellow translucent 0.2; lcaocartoon scale 1; lcaocartoon create s</script> | + | <script>select all;lcaocartoon delete; select (atomno=7); lcaocartoon color yellow translucent 0.2; lcaocartoon scale 1; lcaocartoon create s</script> |
<text>Anzeige des s-Orbitals beim verbundenen H-Atom</text> | <text>Anzeige des s-Orbitals beim verbundenen H-Atom</text> | ||
</item> | </item> | ||
+ | <vertical>true</vertical> | ||
</jmolRadioGroup> | </jmolRadioGroup> | ||
− | |||
− | |||
− | |||
− | |||
− | |||
− | |||
− | |||
− | |||
− | |||
</jmol> | </jmol> | ||
'''Betrachtung der verschiedenen Bindungsarten im Benzol-Molekül:''' | '''Betrachtung der verschiedenen Bindungsarten im Benzol-Molekül:''' | ||
− | |||
<jmol> | <jmol> | ||
− | < | + | <jmolRadioGroup> |
− | + | <vertical>true</vertical> | |
− | + | <item> | |
− | + | <script>select all; lcaocartoon delete; select (atomno=1); lcaocartoon color orange translucent 0.2; lcaocartoon scale 1; lcaocartoon create sp2c; select (atomno=7); lcaocartoon color yellow translucent 0.2; lcaocartoon scale 1; lcaocartoon create s</script> | |
− | + | <text>σ-Bindung zwischen einem C-Atom und dem verbundenen H-Atom</text> | |
− | < | + | </item> |
− | < | + | <item> |
− | + | <script>select all; lcaocartoon delete; select (atomno=1); lcaocartoon color orange translucent 0.2; lcaocartoon scale 1; lcaocartoon create sp2b; select (atomno=6); lcaocartoon color orange translucent 0.2; lcaocartoon scale 1; lcaocartoon create sp2a;</script> | |
− | + | <text>σ-Bindung zwischen den C-Atomen 1 und 2</text> | |
− | + | </item> | |
− | + | <item> | |
− | + | <script>select all; lcaocartoon delete; select (atomno=1),(atomno=2),(atomno=3),(atomno=4),(atomno=5),(atomno=6); lcaocartoon color orange translucent 0.2; lcaocartoon scale 1; lcaocartoon create sp2a;lcaocartoon create sp2b; lcaocartoon create sp2c; select (atomno=7),(atomno=8),(atomno=9),(atomno=10),(atomno=11),(atomno=12); lcaocartoon color yellow translucent 0.2; lcaocartoon scale 1; lcaocartoon create s</script> | |
− | < | + | <text>Alle σ-Bindungen im gesamten Molekül</text> |
− | < | + | </item> |
− | + | <item> | |
− | + | <script>select all; lcaocartoon delete; select (atomno=1),(atomno=6); lcaocartoon color blue translucent 0.1; lcaocartoon scale 1.9; lcaocartoon create pz;</script> | |
− | + | <text>π-Bindung zwischen den C-Atomen 1 und 2</text> | |
− | + | </item> | |
− | + | <item> | |
− | < | + | <script>select all; lcaocartoon delete; select (atomno=4), (atomno=5); lcaocartoon color blue translucent 0.1; lcaocartoon scale 1.9; lcaocartoon create pz; select (atomno=5); lcaocartoon color blue translucent 0.1; lcaocartoon scale 1.9; lcaocartoon create pz;</script> |
− | < | + | <text>π-Bindung zwischen den C-Atomen 3 und 4</text> |
− | + | </item> | |
− | + | <item> | |
− | + | <script>select all; lcaocartoon delete; select (atomno=2), (atomno=3); lcaocartoon color blue translucent 0.1; lcaocartoon scale 1.9; lcaocartoon create pz;</script> | |
− | + | <text>π-Bindung zwischen den C-Atomen 5 und 6</text> | |
− | + | </item> | |
+ | <item> | ||
+ | <script>select all; lcaocartoon delete; select (atomno=1),(atomno=2),(atomno=3),(atomno=4),(atomno=5),(atomno=6); lcaocartoon color blue translucent 0.1; lcaocartoon scale 1.9; lcaocartoon create pz;</script> | ||
+ | <text>π-Bindungen im gesamten Molekül</text> | ||
+ | </item> | ||
+ | </jmolRadioGroup> | ||
</jmol> | </jmol> | ||
|} | |} | ||
+ | |||
+ | [[Kategorie:Orbitalmodell]] | ||
+ | [[Kategorie:Atommodell]] | ||
+ | [[Kategorie:Organische Chemie]] | ||
+ | [[Kategorie:Alkene]] | ||
+ | [[Kategorie:CML-Datei]] | ||
+ | [[Kategorie:Jmol]] |
Aktuelle Version vom 28. November 2016, 16:28 Uhr
Hinweis zur Bedienung: Das Molekül lässt sich mit der Maus (linke Maustaste) drehen. Mit dem Mausrad kann man hinein und hinaus scrollen.
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Darstellung und Sonstiges:
Anzeige der Orbitale bei einem C-Atom und dem verbundenen H-Atom
Betrachtung der verschiedenen Bindungsarten im Benzol-Molekül:
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